Synthesis of asymmetrically substituted 1,4,7,10-tetraazacyclododecanes for the triggered near infrared emission from lanthanide complexes

Borbas, K. Eszter and Bruce, James I. (2006). Synthesis of asymmetrically substituted 1,4,7,10-tetraazacyclododecanes for the triggered near infrared emission from lanthanide complexes. Chemical Communications, 44 pp. 4596–4598.

DOI: https://doi.org/10.1039/b611442c

Abstract

A synthetic strategy to prepare asymmetrically substituted 1,4,7,10-tetrazadodecane derivatives was developed to prepare a novel series of photoactive donor–acceptor quencher triads based on Yb and Nd complexes; a nucleoside quencher is used to regulate the extent of energy transfer between the donor and the acceptor.

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