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Bruce, James; Borbas, K. Eszter and Bodi, Andras
(2007).
DOI: https://doi.org/10.1039/b708940f
Abstract
The synthesis and characterisation of two new cyclen-based near IR-emitting lanthanide complexes are reported; the lanthanides are sensitised by rhodamine, which in turn is excited by energy transfer from a coumarin 2 moiety. Double stranded DNA selectively switches one of the two energy transfer processes off, enabling luminescent Q1 DNA-sensing in the near IR region. The regioselective di-alkylation of the cyclen scaffold is explained with the help of DFT calculations.
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- Item ORO ID
- 8934
- Item Type
- Journal Item
- ISSN
- 0300-9246
- Academic Unit or School
-
Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM) - Depositing User
- James Bruce