Chiral N,O-Ligand/[Cu(OAc)2]-Catalyzed Asymmetric Construction of 4-Aminopyrrolidine Derivatives by 1,3-Dipolar Cycloaddition of Azomethine Ylides with α-Phthalimidoacrylates.

Wang, Zheng; Yu, Xingxin; Tian, Bo-Xue; Payne, Daniel T.; Yang, Wu-Lin; Liu, Yang-Zi; Fossey, John S. and Deng, Wei-Ping (2015). Chiral N,O-Ligand/[Cu(OAc)2]-Catalyzed Asymmetric Construction of 4-Aminopyrrolidine Derivatives by 1,3-Dipolar Cycloaddition of Azomethine Ylides with α-Phthalimidoacrylates. ChemInform, 46(48)

DOI: https://doi.org/10.1002/chin.201548121

Abstract

Among various chiral N,O-ligands tested, the 7-chloro derivative CQI is found to be the optimal one.

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