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Bassindale, Alan Richard; Parker; Taylor, Peter Geoffrey and Watt, Alison Claire
(2003).
DOI: https://doi.org/10.1139/V03-138
URL: http://search.ebscohost.com/login.aspx?direct=true...
Abstract
The products from the reaction of octahydrosilsesquioxane (T-8-H) with different molar ratios of phenol and undec-1-ene or methyl 3,3-dimethylpent-4-enoate (MDP) in the presence of chloroplatinic acid have been analysed by Si-29 NMR spectroscopy. The distribution of the two different pendant groups leads to tetrad patterns where the relative chemical peak intensities reflect the selectivity for particular patterns of substitution. As well as analysing the cause of these tetrad patterns we also discuss how the regioselectivity of hydrosilylation can be determined.
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- Item ORO ID
- 6152
- Item Type
- Journal Item
- ISSN
- 0008-4042
- Keywords
- T-8; Q(8); silsesquioxane; Si-29 NMR; hydrosilylation; tetrad pattern; regioselectivity; statistical modelling
- Academic Unit or School
-
Other Departments > Vice-Chancellor's Office
Other Departments
Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM) - Depositing User
- Astrid Peterkin