An EXAFS study of the formation of a nanoporous metal–organic framework: evidence for the retention of secondary building units during synthesis

Surble, Suzy; Millange, Franck; Serre, Christian; Ferey, Gerard and Walton, Richard I. (2006). An EXAFS study of the formation of a nanoporous metal–organic framework: evidence for the retention of secondary building units during synthesis. Chemical Communications, 14 pp. 1518–1520.

DOI: https://doi.org/10.1039/b600709k

Abstract

EXAFS data measured from amorphous intermediates and crystallisation solutions provides the first evidence that trimeric iron oxide secondary building units remain intact during crystallisation of the metal-organic framework MIL-89 from starting materials to products.

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