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Shipov, A.G.; Kramarova, E.P.; Murasheva, T.P.; Artamkina, O.B.; Negrebetskii, V.V.; Baukov, Yu I.; Pogozhikh, S.A.; Ovchinnikov, Yu E.; Voronkov, M.G.; Bassindale, Alan and Taylor, Peter
(2006).
DOI: https://doi.org/10.1007/s11172-006-0295-y
Abstract
N-(Dimethylfluorosilylmethyl)succinimide (2a) and N-(dimethylfluorosilylmethyl)phthalimide (2b) were synthesized by the Si-N bond cleavage in readily accessible N-(dimethylimidosilylmethyl)imides with BF3 etherate. Analogously, (O -> Si)-chelated 1-(dimethyl-fluorosilylmethyl)-2-pyrrolidone was prepared from 1-(dimethylmorpholinosilylmethyl)-2-pyrrolidone. X-ray diffraction study demonstrated that the silicon atom in the crystals of 2b is pentacoordinated.