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Lane, Jonathan
(1998).
DOI: https://doi.org/10.21954/ou.ro.0000e210
Abstract
The current paper recycling processes are surveyed pointing out the major stages and the variety of chemical/mechanical treatments the fibres undergo. The reduction or replacement of chemical/mechanical treatments presents possible advantages in prolonging fibre life.
The results from recycled office waste which has been treated with ultrasound show a change in the particle size distribution of toner particles - making these particles easier to remove using established flotation techniques. Particle size distributions were measured using image analysis on thin (20gsm) paper handsheets. To establish the affect of sonication on fibres, a variety of virgin fibres were obtained from UK Paper, Sittingbourne.
Results from virgin fibres which have been treated using ultrasound indicate an absence of cutting compared to conventional techniques. Fibres were found to have the same average length (0.6mm) after ultrasound treatment as the control sample, refined fibres were reduced to approximately 0.3 mm in length. Freeness decreased in both virgin sonicated and refined sonicated samples. The decrease in freeness was accompanied by an increase in the strength properties of both categories of fibres.
Experiments with a prepared office waste furnish showed that ultrasonic treatment could decrease the size distribution of fused toner particles. The control sample had an average size of 80.9 um, after 1 minute sonication this was decreased to 54.9) um, decreasing further to 46.8)um after 2 minutes sonication.
After demonstrating that ultrasound could decrease the particle distribution of the prepared office waste a more realistic and variable furnish was used. The experiments were conducted at room temperature, 50°C and 75°C. These temperatures were chosen to study the behaviour of fused toners as it approaches and exceeds its glass transition point, essentially the melting point of an amorphous polymer. It was found that the toner is easier to remove as the glass transition temperature is approached. Ultrasound is effective in breaking up large toner particles and detaching particles smaller than 25 microns in diameter.