VUV photo-absorption cross-section for CCl₂F₂

Limão Viera, P.; Eden, S.; Kendall, P. A.; Mason, N. J. and Hoffmann, S. V. (2002). VUV photo-absorption cross-section for CCl₂F₂. Chemical Physics Letters, 364(5-6) pp. 535–541.

DOI: https://doi.org/10.1016/S0009-2614(02)01304-0

Abstract

The photo-absorption spectrum of CCl2F2 has been measured using synchrotron radiation in the range 5.5–11 eV (225>λ>110 nm). Electronic state assignments have been suggested for each of the observed absorption bands incorporating both valence and Rydberg transitions. The high resolution achieved has allowed vibrational series in one of these bands to be assigned for the first time. The measured VUV cross-sections may be used to derive the photolysis rate of CCl₂F₂ in the terrestrial atmosphere.

Viewing alternatives

Metrics

Item Actions

Export

You can export this page using these formats Digital Object Identifier - DOI