Elucidation of the bonding in Mn(η2-SiH) complexes by charge density analysis and T1 NMR measurements: asymmetric oxidative addition and anomeric effects at silicon

Scherer, Wolfgang; Eickerling, Georg; Tafipolsky, Maxim; McGrady, G. Sean; Sirsch, Peter and Chatterton, Nicholas P. (2006). Elucidation of the bonding in Mn(η2-SiH) complexes by charge density analysis and T1 NMR measurements: asymmetric oxidative addition and anomeric effects at silicon. Chemical Communications(28) pp. 2986–2988.

DOI: https://doi.org/10.1039/b604843a

Abstract

The bonding in Mn(η2-SiH) complexes is interpreted in terms of an asymmetric oxidative addition whose extent is controlled by the substitution pattern at the hypercoordinate silicon centre, and especially by the ligand trans to the η2-coordinating SiH moiety.

Viewing alternatives

Metrics

Public Attention

Altmetrics from Altmetric

Number of Citations

Citations from Dimensions

Item Actions

Export

About