Structure of the elusive hydrido(methylcyclopentadienyl)dicarbonylmanganate(I) anion, [(η⁵-C₅H₄Me)Mn(CO)₂H]-, as determined by single-crystal X-ray diffraction

Chatterton, Nicholas P.; Guilera, Gemma and McGrady, G. Sean (2004). Structure of the elusive hydrido(methylcyclopentadienyl)dicarbonylmanganate(I) anion, [(η⁵-C₅H₄Me)Mn(CO)₂H]-, as determined by single-crystal X-ray diffraction. Organometallics, 23(5) pp. 1165–1167.

DOI: https://doi.org/10.1021/om034293r

Abstract

The structure of [K(18-crown-6)][(η⁵-C₅H₄Me)Mn(CO)₂H] has been determined by single-crystal X-ray diffraction, and the anion is found to adopt a three-legged piano-stool geometry. Its structure is compared with those of related bridging hydride and σ-bond complexes.

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