Cationic complexes of silicon and germanium with (O,S)-chelate ligands

Kalashnikova, Natalia A.; Bylikin, Sergey Yu.; Korlyukov, Aleksander A.; Shipov, Aleksander G.; Baukov, Yuri I.; Taylor, Peter G. and Bassindale, Alan R. (2012). Cationic complexes of silicon and germanium with (O,S)-chelate ligands. Dalton transactions, 2012(41) pp. 12681–12682.

DOI: https://doi.org/10.1039/c2dt31554h

Abstract

Synthesis and X-ray diffraction study of cationic bischelates MeSi(SCH₂CONMe₂)₂⁺Cl^- and MeGe(SCH₂CONMe₂)₂⁺Br^- are reported. According to X-ray data, the Si and Ge atoms in these compounds have distorted TBP environments with two coordinating oxygen atoms in axial positions.

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• Item ORO ID
• 34654
• Item Type
• Journal Item
• ISSN
• 1477-9234
• Project Funding Details

• Funded Project Name	Project ID	Funding Body
  Not Set	Not Set	Russian Foundation for Basic Research (grant No. 11-03-00655)

• Academic Unit or School
• Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
  Faculty of Science, Technology, Engineering and Mathematics (STEM)
  Other Departments > Vice-Chancellor's Office
  Other Departments
• Copyright Holders
• © 2012 The Royal Society of Chemistry
• Depositing User
• Peter Taylor