Cationic complexes of silicon and germanium with (O,S)-chelate ligands

Kalashnikova, Natalia A.; Bylikin, Sergey Yu.; Korlyukov, Aleksander A.; Shipov, Aleksander G.; Baukov, Yuri I.; Taylor, Peter G. and Bassindale, Alan R. (2012). Cationic complexes of silicon and germanium with (O,S)-chelate ligands. Dalton transactions, 2012(41) pp. 12681–12682.

DOI: https://doi.org/10.1039/c2dt31554h

Abstract

Synthesis and X-ray diffraction study of cationic bischelates MeSi(SCH₂CONMe₂)₂⁺Cl^- and MeGe(SCH₂CONMe₂)₂⁺Br^- are reported. According to X-ray data, the Si and Ge atoms in these compounds have distorted TBP environments with two coordinating oxygen atoms in axial positions.

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