Iron-57 Mössbauer spectroscopic study of fluorinated strontium orthoferrite

Berry, F. J.; Moore, E. A.; Ren, X.; Helgason, Ö.; Thomas, M. F. and Shim, S. (2008). Iron-57 Mössbauer spectroscopic study of fluorinated strontium orthoferrite. Hyperfine Interactions, 185(1-3) pp. 111–114.

DOI: https://doi.org/10.1007/s10751-008-9818-2

Abstract

The 57Fe Mössbauer spectra have been recorded at 300 K from an Fe4+  -containing oxygen-deficient perovskite-related SrFeO3 phase and its fluorinated derivative. The fluorinated phase shows complex magnetically split hyperfine patterns reflecting the interactions between Fe3+   ions which are not possible in oxides containing Fe4+  . The 57Fe Mössbauer spectra recorded in situ above 300 K enable the determination of a magnetic ordering temperature of 685 ± 5 K for SrFeO2F.

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