Mechanism of hydrolysis of substituted N-thiazolylcarbamate esters in OH- solutions

Araujo, M. E. M.; Norberto, F.; Pamplona, T. and Iley, J. (2006). Mechanism of hydrolysis of substituted N-thiazolylcarbamate esters in OH- solutions. Journal of Chemical Research, 2006(10), pp. 664–667.

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Abstract

Substituted secondary N-thiazolylcarbamate esters and some tertiary N-methyl, N-thiazolyl carbamate esters have been synthesised and the mechanism of the OH- catalysed hydrolyses investigated. These proved to be E1cB and BAc2 respectively, and this behaviour was compared with that of other carbamates.

Item Type:	Journal Article
ISSN:	0308-2342
Keywords:	thiazolyl carbamate esters; hydrolysis; Hammett correlation
Academic Unit/Department:	Science > Life, Health and Chemical Sciences
Item ID:	8240
Depositing User:	James Iley
Date Deposited:	13 Jun 2008
Last Modified:	02 Dec 2010 20:00
URI:	http://oro.open.ac.uk/id/eprint/8240

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