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Mechanism of hydrolysis of substituted N-thiazolylcarbamate esters in OH- solutions

Araujo, M. E. M.; Norberto, F.; Pamplona, T. and Iley, J. (2006). Mechanism of hydrolysis of substituted N-thiazolylcarbamate esters in OH- solutions. Journal of Chemical Research, 2006(10) pp. 664–667.

URL: http://www.ingentaconnect.com/content/stl/jcr/2006...
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Abstract

Substituted secondary N-thiazolylcarbamate esters and some tertiary N-methyl, N-thiazolyl carbamate esters have been synthesised and the mechanism of the OH- catalysed hydrolyses investigated. These proved to be E1cB and BAc2 respectively, and this behaviour was compared with that of other carbamates.

Item Type: Journal Article
ISSN: 0308-2342
Keywords: thiazolyl carbamate esters; hydrolysis; Hammett correlation
Academic Unit/Department: Science > Life, Health and Chemical Sciences
Item ID: 8240
Depositing User: James Iley
Date Deposited: 13 Jun 2008
Last Modified: 02 Dec 2010 20:00
URI: http://oro.open.ac.uk/id/eprint/8240
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