Mechanism of hydrolysis of substituted N-thiazolylcarbamate esters in OH- solutions

Araujo, M. E. M.; Norberto, F.; Pamplona, T. and Iley, J. (2006). Mechanism of hydrolysis of substituted N-thiazolylcarbamate esters in OH- solutions. Journal of Chemical Research, 2006(10) pp. 664–667.

DOI: https://doi.org/10.3184/030823406779173578

URL: http://www.ingentaconnect.com/content/stl/jcr/2006...

Abstract

Substituted secondary N-thiazolylcarbamate esters and some tertiary N-methyl, N-thiazolyl carbamate esters have been synthesised and the mechanism of the OH- catalysed hydrolyses investigated. These proved to be E1cB and BAc2 respectively, and this behaviour was compared with that of other carbamates.

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About

• Item ORO ID
• 8240
• Item Type
• Journal Item
• ISSN
• 0308-2342
• Keywords
• thiazolyl carbamate esters; hydrolysis; Hammett correlation
• Academic Unit or School
• Other Departments > Business Development Unit
  Other Departments
• Depositing User
• James Iley