Copy the page URI to the clipboard
Negrebetskiy, Vadim V.; Korlyukov, Alexander A.; Bylikin, Sergey Yu; Tarasenko, Dmitry V.; Kramarova, Eugenija P.; Bassindale, Alan R.; Taylor, Peter G. and Baukov, Yuri I.
(2022).
DOI: https://doi.org/10.1016/j.jorganchem.2021.122163
Abstract
Halogen exchange reactions between hexacoordinate tin dihalides (LnCH2)2SnX2 and (LnCH2)2SnY2 (LnCH2 = C,O-chelate n-membered lactamomethyl ligand, n = 5–7, X, Y = Cl, Br, I) produce mixed dihalides (LnCH2)2SnXY. Along with the signals of original complexes, NMR 119Sn spectra of solutions containing two different homodihalides show the third signal with a median chemical shift. The results of NMR monitoring studies, conductivity data and quantum-chemical calculations suggest that mixed dihalides readily form in solutions, although these complexes have not been isolated as individual compounds.
Viewing alternatives
Download history
Metrics
Public Attention
Altmetrics from AltmetricNumber of Citations
Citations from DimensionsItem Actions
Export
About
- Item ORO ID
- 80022
- Item Type
- Journal Item
- ISSN
- 0022-328X
- Academic Unit or School
-
Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM) - Copyright Holders
- © 2021 Elsevier B.V. All rights reserved.
- Depositing User
- ORO Import