Griffin, Michael; Shakespeare, Stephen; Shepherd, Helena J.; Harding, Charles J.; Létard, Jean-François.; Desplanches, Cédric; Goeta, Andrés E.; Howard, Judith A.K.; Powell, Annie K.; Mereacre, Valeriu; Garcia, Yann; Naik, Anil D.; Müller-Bunz, Helge and Morgan, Grace G.
(2011).
A symmetry-breaking spin-state transition in iron(III).
Angewandte Chemie (International Edition), 50(4),
pp. 896–900.
Abstract
Stepping up: A two-step magnetic spin transition with accompanying structural phase transitions is reported for the first time for FeIII. The transitions are observed at 187 K and 90 K on cooling with a hysteretic transition recorded upon heating during the first crossover at 106 K. The intermediate phase persists over 97 K and contains an unprecedented [HS-HS-LS] motif with tripling of the unit cell.
| Item Type: |
Journal Article
|
| Copyright Holders: |
2011 Wiley-VCH |
| ISSN: |
1521-3773 |
| Extra Information: |
Special Issue: Women in Chemistry |
| Keywords: |
iron; magnetism; phase transitions; spin crossover; symmetry breaking |
| Academic Unit/Department: |
Science > Life, Health and Chemical Sciences |
| Related URLs: |
|
| Item ID: |
7630 |
| Depositing User: |
Charlie Harding
|
| Date Deposited: |
23 Oct 2012 08:55 |
| Last Modified: |
10 Apr 2013 13:33 |
| URI: |
http://oro.open.ac.uk/id/eprint/7630 |
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