Synthesis and structure determination of the new oxide fluoride BaFeO₂F

Heap, Richard; Slater, Peter R.; Berry, Frank J.; Helgason, Orn and Wright, Adrian J. (2007). Synthesis and structure determination of the new oxide fluoride BaFeO₂F. Solid State Communications, 141(8) pp. 467–470.

DOI (Digital Object Identifier) Link:	http://dx.doi.org/10.1016/j.ssc.2006.11.037
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Abstract

Low temperature fluorination of BaFeO_3−x using poly(vinylidene fluoride) leads to the formation of the oxide fluoride BaFeO₂F. Mössbauer spectroscopy shows that this phase exhibits magnetic ordering at room temperature due to interactions between the Fe³+ ions, with an ordering temperature of 645 (±5) K. Neutron diffraction studies show that the phase has cubic symmetry and confirm the presence of magnetic ordering (G-type antiferromagnetic) at room temperature.

Item Type:	Journal Article
ISSN:	0038-1098
Keywords:	magnetically ordered materials; oxide fluorides; Mössbauer spectroscopy; chemical synthesis; crystal structure and symmetry
Academic Unit/Department:	Science > Life, Health and Chemical Sciences
Item ID:	6227
Depositing User:	Frank Berry
Date Deposited:	16 Jan 2007
Last Modified:	02 Dec 2010 19:56
URI:	http://oro.open.ac.uk/id/eprint/6227
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