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Heap, Richard; Slater, Peter R.; Berry, Frank J.; Helgason, Orn and Wright, Adrian J.
(2007).
DOI: https://doi.org/10.1016/j.ssc.2006.11.037
Abstract
Low temperature fluorination of BaFeO3−x using poly(vinylidene fluoride) leads to the formation of the oxide fluoride BaFeO2F. Mössbauer spectroscopy shows that this phase exhibits magnetic ordering at room temperature due to interactions between the Fe3+ ions, with an ordering temperature of 645 (±5) K. Neutron diffraction studies show that the phase has cubic symmetry and confirm the presence of magnetic ordering (G-type antiferromagnetic) at room temperature.
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About
- Item ORO ID
- 6227
- Item Type
- Journal Item
- ISSN
- 0038-1098
- Keywords
- magnetically ordered materials; oxide fluorides; Mössbauer spectroscopy; chemical synthesis; crystal structure and symmetry
- Academic Unit or School
-
Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM) - Depositing User
- Frank Berry