Heap, Richard; Slater, Peter R.; Berry, Frank J.; Helgason, Orn and Wright, Adrian J.
|DOI (Digital Object Identifier) Link:||http://doi.org/10.1016/j.ssc.2006.11.037|
|Google Scholar:||Look up in Google Scholar|
Low temperature fluorination of BaFeO3−x using poly(vinylidene fluoride) leads to the formation of the oxide fluoride BaFeO2F. Mössbauer spectroscopy shows that this phase exhibits magnetic ordering at room temperature due to interactions between the Fe3+ ions, with an ordering temperature of 645 (±5) K. Neutron diffraction studies show that the phase has cubic symmetry and confirm the presence of magnetic ordering (G-type antiferromagnetic) at room temperature.
|Item Type:||Journal Article|
|Keywords:||magnetically ordered materials; oxide fluorides; Mössbauer spectroscopy; chemical synthesis; crystal structure and symmetry|
|Academic Unit/Department:||Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM)
|Depositing User:||Frank Berry|
|Date Deposited:||16 Jan 2007|
|Last Modified:||02 Aug 2016 13:02|
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