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The formation of metal antimonates by mechanical milling and the conversion of alpha-Sb2O4 to beta-Sb2O

Berry, Frank and Ren, X. (2004). The formation of metal antimonates by mechanical milling and the conversion of alpha-Sb2O4 to beta-Sb2O. Journal of Materials Science, 39(4) pp. 1179–1183.

DOI (Digital Object Identifier) Link: http://dx.doi.org/10.1023/B:JMSC.0000013873.04501.52
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Abstract

The mechanical milling of alpha-Fe2O3 or V2O5 with Sb2O3 results in the formation of small particle FeSbO4 or VSbO4. Milling also induces the conversion of cubic Sb2O3 to the orthorhombic modification and the transformation of alpha-Sb2O4 to beta-Sb2O4. The milling-induced alpha- to beta-Sb2O4 phase transition is even more facile in the presence of vanadium or iron. (C) 2004 Kluwer Academic Publishers.

Item Type: Journal Article
ISSN: 0022-2461
Extra Information: Some of the symbols may not have transferred correctly into this bibliographic record and/or abstract.
Keywords: iron antimonate; catalysts; system
Academic Unit/Department: Science > Life, Health and Chemical Sciences
Item ID: 6144
Depositing User: Astrid Peterkin
Date Deposited: 05 Jan 2007
Last Modified: 02 Dec 2010 19:55
URI: http://oro.open.ac.uk/id/eprint/6144
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