Manzhos, Sergei; Romanescu, Constantin; Loock, Hans-Peter and Underwood, Jonathan G.
Two-photon state selection and angular momentum polarization probed by velocity map imaging: Application to H atom photofragment angular distributions from the photodissociation of two-photon state selected HCl and HBr.
Journal of Chemical Physics, 121(23) pp. 11802–11809.
Full text available as:
A formalism for calculating the angular momentum polarization of an atom or a molecule following two-photon excitation of a J-selected state is presented. This formalism is used to interpret the H atom photofragment angular distributions from single-photon dissociation of two-photon rovibronically state selected HCl and HBr prepared via a Q-branch transition. By comparison of the angular distributions measured using the velocity map imaging technique with the theoretical model it is shown that single-photon dissociation of two-photon prepared states can be used for pathway identification, allowing for the identification of the virtual state symmetry in the two-photon absorption and/or the symmetry of the dissociative state. It is also shown that under conditions of excitation with circularly polarized light, or for excitation via non-Q-branch transitions with linearly polarized light the angular momentum polarization is independent of the dynamics of the two-photon transition and analytically computable.©2004 American Institute of Physics.
||2004 American Institute of Physics
||laser-induced fluorescence; enhanced MPI spectra; molecular photodissociation; nonresonant excitation; diatomic-molecules; reaction dynamics; hydrogen bromide; alignment; orientation; population
||Science > Physical Sciences
||22 Dec 2006
||14 Jan 2016 21:26
|Share this page:
Actions (login may be required)