Widatallah, H.M.; Ren, X.-L. and Al-Omari, I.A.
(2006).
The influence of TiO2 polymorph, mechanical milling and subsequent sintering on the formation of Ti-substituted spinel-related Li0.5Fe2.5O4.
Journal of Materials Science, 41(19)
pp. 6333–6338.
Abstract
Single-phased spinel-related titanium-substituted Li0.5Fe2.5O4 has been synthesized by sintering in air a mechanically pre-milled mixture of lithium carbonate, corundum-related iron (III) oxide and the rutile polymorph of titanium (IV) oxide at 700 °C (12 h). This temperature is ca. 450–500 °C less than the temperatures at which the material is normally prepared by conventional ceramic techniques. On replacing the rutile polymorph of titanium (IV) oxide in the pre-milled mixture by the anatase form the formation of single-phased titanium-substituted Li0.5Fe2.5O4 was not achieved even after sintering the mixture at 1,000 °C (12 h).
| Item Type: |
Journal Article
|
| ISSN: |
0022-2461 |
| Extra Information: |
Some of the symbols may not have transferred correctly into this bibliographic record and/or abstract. |
| Academic Unit/Department: |
Other Departments > Other Departments |
| Item ID: |
6062 |
| Depositing User: |
Astrid Peterkin
|
| Date Deposited: |
19 Dec 2006 |
| Last Modified: |
02 Dec 2010 19:55 |
| URI: |
http://oro.open.ac.uk/id/eprint/6062 |
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