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Ground-based detection of a cloud of methanol from Enceladus: when is a biomarker not a biomarker?

Drabek-Maunder, E.; Greaves, J.; Fraser, H. J.; Clements, D. L. and Alconcel, L.-N. (2019). Ground-based detection of a cloud of methanol from Enceladus: when is a biomarker not a biomarker? International Journal of Astrobiology, 18(1) pp. 25–32.

DOI (Digital Object Identifier) Link: https://doi.org/10.1017/S1473550417000428
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Abstract

Saturn’s moon Enceladus has vents emerging from a sub-surface ocean, offering unique probes into the liquid environment. These vents drain into the larger neutral torus in orbit around Saturn. We present a methanol (CH3OH) detection observed with IRAM 30-m from 2008 along the line-of-sight through Saturn’s E-ring. Additionally, we also present supporting observations from the Herschel public archive of water (ortho-H2O; 1669.9 GHz) from 2012 at a similar elongation and line-of-sight. The CH3OH 5(1,1)-4(1,1) transition was detected at 5.9σ confidence. The line has 0.43 km s−1 width and is offset by +8.1 km s−1 in the moon’s reference frame. Radiative transfer models allow for gas cloud dimensions from 1750 km up to the telescope beam diameter ∼73 000 km. Taking into account the CH3OH lifetime against solar photodissociation and the redshifted line velocity, there are two possible explanations for the CH3OH emission: methanol is primarily a secondary product of chemical interactions within the neutral torus that: (1) spreads outward throughout the E-ring or (2) originates from a compact, confined gas cloud lagging Enceladus by several km s−1. We find either scenario to be consistent with significant redshifted H2O emission (4σ) measured from the Herschel public archive. The measured CH3OH:H2O abundance (>0.5%) significantly exceeds the observed abundance in the direct vicinity of the vents (∼0.01%), suggesting CH3OH is likely chemically processed within the gas cloud with methane (CH4) as its parent species.

Item Type: Journal Item
Copyright Holders: 2017 Cambridge University Press
ISSN: 1475-3006
Keywords: astrobiology; astrochemistry; planets and satellites: Enceladus; submillimeter:general
Academic Unit/School: Faculty of Science, Technology, Engineering and Mathematics (STEM) > Physical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM)
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Item ID: 59554
Depositing User: ORO Import
Date Deposited: 07 Mar 2019 14:24
Last Modified: 01 Apr 2019 11:40
URI: http://oro.open.ac.uk/id/eprint/59554
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