The Open UniversitySkip to content
 

A Manganese(III) Complex That Exhibits Spin Crossover Triggered by Geometric Tuning

Morgan, Grace G.; Murnaghan, Kevin D.; Müller-Bunz, Helge; McKee, Vickie and Harding, Charles J. (2006). A Manganese(III) Complex That Exhibits Spin Crossover Triggered by Geometric Tuning. Angewandte Chemie International Edition, 45(43) pp. 7192–7195.

DOI (Digital Object Identifier) Link: http://doi.org/10.1002/anie.200601823
Google Scholar: Look up in Google Scholar

Abstract

Room to expand: A rare example of thermal spin crossover in a MnIII complex is accompanied by elongation of the bonds to the equatorial N4 donor set upon warming (see scheme; Mn purple, N blue, O red), which is consistent with population of the dx2-y2 orbital. The spin crossover was observed for an N4(O-)2 donor set with axial oxygen donors, whereas only a temperature-independent high-spin state was observed with these donors in a cis arrangement.

Item Type: Journal Article
ISSN: 1521-3773
Keywords: ligand design; magnetic properties; manganese; molecular; switches; spin crossover
Academic Unit/Department: Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM)
Item ID: 5791
Depositing User: Charlie Harding
Date Deposited: 03 Nov 2006
Last Modified: 02 Aug 2016 13:01
URI: http://oro.open.ac.uk/id/eprint/5791
Share this page:

Altmetrics

Scopus Citations

▼ Automated document suggestions from open access sources

Actions (login may be required)

Policies | Disclaimer

© The Open University   + 44 (0)870 333 4340   general-enquiries@open.ac.uk