Morgan, Grace G.; Murnaghan, Kevin D.; Müller-Bunz, Helge; McKee, Vickie and Harding, Charles J.
|DOI (Digital Object Identifier) Link:||http://doi.org/10.1002/anie.200601823|
|Google Scholar:||Look up in Google Scholar|
Room to expand: A rare example of thermal spin crossover in a MnIII complex is accompanied by elongation of the bonds to the equatorial N4 donor set upon warming (see scheme; Mn purple, N blue, O red), which is consistent with population of the dx2-y2 orbital. The spin crossover was observed for an N4(O-)2 donor set with axial oxygen donors, whereas only a temperature-independent high-spin state was observed with these donors in a cis arrangement.
|Item Type:||Journal Article|
|Keywords:||ligand design; magnetic properties; manganese; molecular; switches; spin crossover|
|Academic Unit/Department:||Science > Life, Health and Chemical Sciences
|Depositing User:||Charlie Harding|
|Date Deposited:||03 Nov 2006|
|Last Modified:||14 Jan 2016 16:23|
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