Widatallah, Hisham M. and Berry, Frank J.
The influence of mechanical milling and subsequent calcination on the formation of lithium ferrites.
Journal of Solid State Chemistry, 164(2) pp. 230–236.
The influence of ball milling and subsequent calcination of a 2.5:1 molar mixture of alpha-Fe2O3 and Li2CO3 on the formation of lithium ferrites has been investigated. Premilling was found to considerably lower the temperature at which the lithium ferrites LiFeO2 and LiFe5O8 are formed. A beta-to-alpha-phase transition in LiFe5O8 was found to take place on cooling from ca. 1000degreesC depending on the milling history and cooling regime. (C) 2002 Elsevier Science (USA).
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