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Johnson, David A. and Nelson, Peter G.
(2018).
DOI: https://doi.org/10.1007/s10698-017-9291-6
Abstract
The valencies of the lanthanides vary more than was once thought. In addition to valencies associated with a half-full shell, there are valencies associated with a quarter- and three-quarter-full shell. This can be explained on the basis of Slater’s theory of many-electron atoms. The same theory explains the variation in complexing constants in the trivalent state (the “tetrad effect”). Valency in metallic and organometallic compounds is also discussed.
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- Item ORO ID
- 53772
- Item Type
- Journal Item
- ISSN
- 1572-8463
- Keywords
- Lanthanide; Valency; f shell; Ionization energy; Hydration energy; Coulomb energy; Exchange energy; Nephelauxetic effect; Tetrad effect
- Academic Unit or School
-
Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM) - Copyright Holders
- © 2017 The Authors
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