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Dissociative electron attachment to formic acid (HCOOH)

Pelc, Andrzej; Sailer, Wolfgang; Scheier, Paul; Probst, Michael; Mason, Nigel J.; Illenberger, Eugen and Märk, Tilmann D. (2002). Dissociative electron attachment to formic acid (HCOOH). Chemical Physics Letters, 361(3-4) pp. 277–284.

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Dissociative electron attachment to formic acid as a fundamental center in enzymatic activity is studied. A prominent resonance is observed peaking at 1.25 eV which decomposes into the formate anion HCOO− and a hydrogen radical. Resonances at higher energy are associated with O− and OH− formation on a considerably smaller intensity scale. On the basis of high level ab initio calculations, the low energy feature arises from different closely spaced single particle shape resonances with no specific valence character. The HCOO− ion yield carries structure which is tentatively ascribed to vibrational excitation in the formate anion.

Item Type: Journal Article
ISSN: 0009-2614
Academic Unit/Department: Science > Physical Sciences
Interdisciplinary Research Centre: Centre for Earth, Planetary, Space and Astronomical Research (CEPSAR)
Item ID: 4479
Depositing User: Users 6827 not found.
Date Deposited: 06 Jul 2006
Last Modified: 14 Jan 2016 16:02
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