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Elucidation of the bonding in Mn(η2-SiH) complexes by charge density analysis and T1 NMR measurements: asymmetric oxidative addition and anomeric effects at silicon

Scherer, Wolfgang; Eickerling, Georg; Tafipolsky, Maxim; McGrady, G. Sean; Sirsch, Peter and Chatterton, Nicholas P. (2006). Elucidation of the bonding in Mn(η2-SiH) complexes by charge density analysis and T1 NMR measurements: asymmetric oxidative addition and anomeric effects at silicon. Chemical Communications(28) pp. 2986–2988.

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DOI (Digital Object Identifier) Link: https://doi.org/10.1039/b604843a
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Abstract

The bonding in Mn(η2-SiH) complexes is interpreted in terms of an asymmetric oxidative addition whose extent is controlled by the substitution pattern at the hypercoordinate silicon centre, and especially by the ligand trans to the η2-coordinating SiH moiety.

Item Type: Journal Item
Copyright Holders: 2006 The Royal Society of Chemistry
ISSN: 1364-548X
Academic Unit/School: Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM)
Item ID: 43980
Depositing User: Nicholas Chatterton
Date Deposited: 13 Aug 2015 11:01
Last Modified: 19 Jun 2020 19:30
URI: http://oro.open.ac.uk/id/eprint/43980
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