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An efficient design for the rigid assembly of four bidentate chromophores in water-stable highly luminescent lanthanide complexes

Chatterton, Nicholas; Bretonnière, Yann; Pécaut, Jacques and Mazzanti, Marinella (2005). An efficient design for the rigid assembly of four bidentate chromophores in water-stable highly luminescent lanthanide complexes. Angewandte Chemie International Edition, 44(46) pp. 7595–7598.

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DOI (Digital Object Identifier) Link: https://doi.org/10.1002/anie.200502231
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Abstract

A simple bridge solves a difficult architectural problem. Ligand H4tpaen, with an ethylenediamine backbone that has ten donor atoms, yields ten-coordinate lanthanide complexes, thus providing highly effective protection of the metal center from interaction with the solvent molecules. As a result, the EuIII and TbIII complexes of (tpaen)4− show a bright and long-lived luminescence in H2O combined with high solubility and stability.

Item Type: Journal Item
Copyright Holders: 2005 Wiley-VCH Verlag GmbH & Co.
ISSN: 1521-3773
Keywords: carboxylate ligands; lanthanides; luminescence; N ligands; sensitizers
Academic Unit/School: Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM)
Item ID: 43979
Depositing User: Nicholas Chatterton
Date Deposited: 13 Aug 2015 10:50
Last Modified: 19 Jun 2020 19:29
URI: http://oro.open.ac.uk/id/eprint/43979
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