The Open UniversitySkip to content
 

Structure of the elusive hydrido(methylcyclopentadienyl)dicarbonylmanganate(I) anion, [(η5-C5H4Me)Mn(CO)2H]-, as determined by single-crystal X-ray diffraction

Chatterton, Nicholas P.; Guilera, Gemma and McGrady, G. Sean (2004). Structure of the elusive hydrido(methylcyclopentadienyl)dicarbonylmanganate(I) anion, [(η5-C5H4Me)Mn(CO)2H]-, as determined by single-crystal X-ray diffraction. Organometallics, 23(5) pp. 1165–1167.

Full text available as:
Full text not publicly available (Version of Record)
Due to publisher licensing restrictions, this file is not available for public download
DOI (Digital Object Identifier) Link: https://doi.org/10.1021/om034293r
Google Scholar: Look up in Google Scholar

Abstract

The structure of [K(18-crown-6)][(η5-C5H4Me)Mn(CO)2H] has been determined by single-crystal X-ray diffraction, and the anion is found to adopt a three-legged piano-stool geometry. Its structure is compared with those of related bridging hydride and σ-bond complexes.

Item Type: Journal Item
Copyright Holders: 2004 American Chemical Society
ISSN: 1520-6041
Academic Unit/School: Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM)
Item ID: 43977
Depositing User: Nicholas Chatterton
Date Deposited: 13 Aug 2015 10:15
Last Modified: 08 Dec 2018 01:34
URI: http://oro.open.ac.uk/id/eprint/43977
Share this page:

Metrics

Altmetrics from Altmetric

Citations from Dimensions

Actions (login may be required)

Policies | Disclaimer

© The Open University   contact the OU