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View from the bridge: a pseudo-Jahn-Teller approach to transition metal hydrosilane complexes

Paterson, Martin J.; Chatterton, Nicholas P. and McGrady, G. Sean (2004). View from the bridge: a pseudo-Jahn-Teller approach to transition metal hydrosilane complexes. New Journal of Chemistry, 28(12) pp. 1434–1436.

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DOI (Digital Object Identifier) Link: https://doi.org/10.1039/b412371a
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Abstract

The model complex [Cp(CO)2Mn(SiH4)] has been studied by time-dependent DFT methods: hence, it is shown to be unstable with respect to a pseudo-Jahn–Teller distortion which brings an equatorial Si–H moiety into contact with the Mn centre.

Item Type: Journal Item
Copyright Holders: 2004 The Royal Society of Chemistry and the Centre National de la Rech erche Scientifique
ISSN: 1369-9261
Academic Unit/School: Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM)
Item ID: 43976
Depositing User: Nicholas Chatterton
Date Deposited: 13 Aug 2015 09:55
Last Modified: 07 Dec 2018 10:33
URI: http://oro.open.ac.uk/id/eprint/43976
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