View from the bridge: a pseudo-Jahn-Teller approach to transition metal hydrosilane complexes

Paterson, Martin J.; Chatterton, Nicholas P. and McGrady, G. Sean (2004). View from the bridge: a pseudo-Jahn-Teller approach to transition metal hydrosilane complexes. New Journal of Chemistry, 28(12) pp. 1434–1436.

DOI: https://doi.org/10.1039/b412371a

Abstract

The model complex [Cp(CO)₂Mn(SiH₄)] has been studied by time-dependent DFT methods: hence, it is shown to be unstable with respect to a pseudo-Jahn–Teller distortion which brings an equatorial Si–H moiety into contact with the Mn centre.

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• Item ORO ID
• 43976
• Item Type
• Journal Item
• ISSN
• 1369-9261
• Academic Unit or School
• Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
  Faculty of Science, Technology, Engineering and Mathematics (STEM)
• Copyright Holders
• © 2004 The Royal Society of Chemistry and the Centre National de la Rech erche Scientifique
• Depositing User
• Nicholas Chatterton