Sailer, Wolfgang; Tegeder, Petra; Probst, Michael; Drexel, Herwig; Grill, Verena; Scheier, Paul; Mason, Nigel J.; Illenberger, Eugen and Mark, Tilmann D.
|DOI (Digital Object Identifier) Link:||http://dx.doi.org/10.1016/S0009-2614(01)00814-4|
|Google Scholar:||Look up in Google Scholar|
Dissociative electron attachment (DA) to ClOCl is studied in a high resolution crossed beam experiment. Two complementary ion pairs, Cl−/ClO− and O−/Cl2−, are observed. The Cl−/ClO− pair arises from a simple Cl–OCl bond cleavage with the electron sitting on either of the two fragments. The O−/Cl2− pair is formed by a concerted reaction with the expulsion of O− (or O) and formation of Cl2 (or Cl2−). Ab initio calculations indicate that in low energy electron attachment an electronically excited state of the precursor anion (ClOCl−* (2B2)) is involved.
|Item Type:||Journal Article|
|Copyright Holders:||2001 Elsevier Science B.V.|
|Academic Unit/Department:||Science > Physical Sciences
|Interdisciplinary Research Centre:||Centre for Earth, Planetary, Space and Astronomical Research (CEPSAR)|
|Depositing User:||Users 6827 not found.|
|Date Deposited:||06 Jul 2006|
|Last Modified:||14 Jan 2016 16:01|
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