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Different formation kinetics and photoisomerization behavior of self-assembled monolayers of thiols and dithiolanes bearing azobenzene moieties

Yeung, Chun L.; Charlesworth, Scott; Iqbal, Parvez; Bowen, James; Preece, Jon A. and Mendes, Paula M. (2013). Different formation kinetics and photoisomerization behavior of self-assembled monolayers of thiols and dithiolanes bearing azobenzene moieties. Physical Chemistry Chemical Physics, 15(26) pp. 11014–11024.

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DOI (Digital Object Identifier) Link: https://doi.org/10.1039/c3cp42104j
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Abstract

Self-assembled monolayers (SAMs) containing azobenzene moieties are very attractive for a wide range of applications, including molecular electronics and photonics, bio-interface engineering and sensoring. However, very little is known about the aggregation and photoswitching behavior that azobenzene units undergo during the SAM formation process. Here, we demonstrate that the formation of thiol based SAMs containing azobenzenes (denoted as AzoSH) on gold surfaces is characterised by a two step adsorption kinetics, while a three-step assembly process has been identified for dithiolane-based SAMs containing azobenzenes (denoted AzoSS). The H-aggregation on the AzoSS SAMs was found to be remarkably dependent on the time of self-assembly, with less aggregation as a function of time. While photoisomerization of the AzoSH was suppressed for all different assembly times, the reversible trans–cis photoisomerization of AzoSS SAMs formed over 24 hours was clearly observed upon alternating UV and Vis light irradiation. We contend that detailed information on formation kinetics and related optical properties is of crucial importance for elucidating the photoswitching capabilities of azobenzene based SAMs.

Item Type: Journal Item
Copyright Holders: 2013 Owners Society
ISSN: 1463-9076
Project Funding Details:
Funded Project NameProject IDFunding Body
Not SetF/00094/AWLeverhulme Trust
Not SetNot SetEuropean Regional Development Fund (ERDF)
Academic Unit/School: Faculty of Science, Technology, Engineering and Mathematics (STEM) > Engineering and Innovation
Faculty of Science, Technology, Engineering and Mathematics (STEM)
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Item ID: 43162
Depositing User: James Bowen
Date Deposited: 27 May 2015 15:32
Last Modified: 17 Nov 2016 08:19
URI: http://oro.open.ac.uk/id/eprint/43162
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