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Isotopic composition of carbon and nitrogen in ureilitic fragments of the Almahata Sitta meteorite

Downes, H.; Abernethy, F. A. J.; Smith, C. L.; Ross, A. J.; Verchovsky, A. B.; Grady, M. M.; Jenniskens, P. and Shaddad, M. H. (2015). Isotopic composition of carbon and nitrogen in ureilitic fragments of the Almahata Sitta meteorite. Meteoritics & Planetary Science, 50(2) pp. 255–272.

DOI (Digital Object Identifier) Link: https://doi.org/10.1111/maps.12413
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Abstract

This study characterizes carbon and nitrogen abundances and isotopic compositions in ureilitic fragments of Almahata Sitta. Ureilites are carbon-rich (containing up to 7 wt% C) and were formed early in solar system history, thus the origin of carbon in ureilites has significance for the origin of solar system carbon. These samples were collected soon after they fell, so they are among the freshest ureilite samples available and were analyzed using stepped combustion mass spectrometry. They contained 1.2–2.3 wt% carbon; most showed the major carbon release at temperatures of 600–700 °C with peak values of δ13C from −7.3 to +0.4‰, similar to literature values for unbrecciated (“monomict”) ureilites. They also contained a minor low temperature (≤500 °C) component (δ13C = ca −25‰). Bulk nitrogen contents (9.4–27 ppm) resemble those of unbrecciated ureilites, with major releases mostly occurring at 600–750 °C. A significant lower temperature release of nitrogen occurred in all samples. Main release δ15N values of −53 to −94‰ fall within the range reported for diamond separates and acid residues from ureilites, and identify an isotopically primordial nitrogen component. However, they differ from common polymict ureilites which are more nitrogen-rich and isotopically heavier. Thus, although the parent asteroid 2008TC3 was undoubtedly a polymict ureilite breccia, this cannot be deduced from an isotopic study of individual ureilite fragments. The combined main release δ13C and δ15N values do not overlap the fields for carbonaceous or enstatite chondrites, suggesting that carbon in ureilites was not derived from these sources.

Item Type: Journal Item
Copyright Holders: 2015 The Meteoritical Society
ISSN: 1945-5100
Academic Unit/School: Faculty of Science, Technology, Engineering and Mathematics (STEM) > Physical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM)
Item ID: 42758
Depositing User: Feargus Abernethy
Date Deposited: 14 May 2015 08:57
Last Modified: 07 Dec 2018 10:30
URI: http://oro.open.ac.uk/id/eprint/42758
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