Asymmetric synthesis of chiral α-ferrocenylalkylamines and their use in the preparation of chiral redox-active receptors

Laurent, Pierre; Miyaji, Hidekazu; Collinson, Simon R.; Prokeš, Ivan; Moody, Christopher J.; Tucker, James H. R. and Slawin, Alexandra M. Z. (2002). Asymmetric synthesis of chiral α-ferrocenylalkylamines and their use in the preparation of chiral redox-active receptors. Organic Letters, 4(23) pp. 4037–4040.

DOI: https://doi.org/10.1021/ol020162v

Abstract

A new strategy for the asymmetric synthesis of chiral primary α-ferrocenylalkylamines has been utilized to generate homochiral redox-active receptors that bind chiral carboxylate anions with moderate enantioselectivity and undergo a redox response to complexation.

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About

• Item ORO ID
• 41620
• Item Type
• Journal Item
• ISSN
• 1523-7052
• Keywords
• organometallic reagents; enantioselective synthesis; molecular recognition; organolithium compounds; oxime ethers; amino-acids; 1,2-addition; 1-ferrocenylalkylamines; thiourea
• Academic Unit or School
• Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
  Faculty of Science, Technology, Engineering and Mathematics (STEM)
• Copyright Holders
• © 2002 American Chemical Society
• Depositing User
• Simon Collinson