Asymmetric synthesis of chiral α-ferrocenylalkylamines and their use in the preparation of chiral redox-active receptors

Laurent, Pierre; Miyaji, Hidekazu; Collinson, Simon R.; Prokeš, Ivan; Moody, Christopher J.; Tucker, James H. R. and Slawin, Alexandra M. Z. (2002). Asymmetric synthesis of chiral α-ferrocenylalkylamines and their use in the preparation of chiral redox-active receptors. Organic Letters, 4(23) pp. 4037–4040.

DOI: https://doi.org/10.1021/ol020162v

Abstract

A new strategy for the asymmetric synthesis of chiral primary α-ferrocenylalkylamines has been utilized to generate homochiral redox-active receptors that bind chiral carboxylate anions with moderate enantioselectivity and undergo a redox response to complexation.

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