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A Raman spectroscopic study of organic matter in interplanetary dust particles and meteorites using multiple wavelength laser excitation

Starkey, N. A.; Franchi, I. A. and Alexander, C. M. O'D. (2013). A Raman spectroscopic study of organic matter in interplanetary dust particles and meteorites using multiple wavelength laser excitation. Meteoritics & Planetary Science, 48(10) pp. 1800–1822.

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DOI (Digital Object Identifier) Link: https://doi.org/10.1111/maps.12196
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Abstract

Raman spectroscopy was used to investigate insoluble organic matter (IOM) from a range of chondritic meteorites, and a suite of interplanetary dust particles (IDPs). Three monochromatic excitation wavelengths (473 nm, 514 nm, 632 nm) were applied sequentially to assess variations in meteorite and IDP Raman peak parameters (carbon D and G bands) as a function of excitation wavelength (i.e., dispersion). Greatest dispersion occurs in CVs > OCs > CMs > CRs with type 3 chondrites compared at different excitation wavelengths displaying conformable relationships, in contrast to type 2 chondrites. These findings indicate homogeneity in the structural nature of type 3 chondrite IOM, while organic matter (OM) in type 2 chondrites appears to be inherently more heterogeneous. If type 2 and type 3 chondrite IOM shares a common source, then thermal metamorphism may have a homogenizing effect on the originally more heterogeneous OM. IDP Raman G bands fall on an extension of the trend displayed by chondrite IOM, with all IDPs having Raman parameters indicative of very disordered carbon, with almost no overlap with IOM. The dispersion effect displayed by IDPs is most similar to CMs for the G band, but intermediate between CMs and CRs for the D band. The existence of some overlapping Raman features in the IDPs and IOM indicates that their OM may share a common origin, but the IDPs preserve more pristine OM that may have been further disordered by ion irradiation. H, C, and N isotopic data for the IDPs reveal that the disordered carbon in IDPs corresponds with higher δ15N and lower δ13C.

Item Type: Journal Item
Copyright Holders: 2013 The Meteoritical Society
ISSN: 1945-5100
Project Funding Details:
Funded Project NameProject IDFunding Body
Understanding Origins at the Open University (UO@OU)ST/I001964/1STFC (Science & Technology Facilities Council)
Academic Unit/School: Faculty of Science, Technology, Engineering and Mathematics (STEM) > Physical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM)
Item ID: 38454
Depositing User: Natalie Starkey
Date Deposited: 24 Sep 2013 13:53
Last Modified: 08 Dec 2018 12:10
URI: http://oro.open.ac.uk/id/eprint/38454
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