Bruce, James I.; Parker, David and Tozer, David J.
|DOI (Digital Object Identifier) Link:||http://dx.doi.org/10.1039/b105006k|
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Measurements of the equilibrium constants for ligand exchange (MeCN, 295 K) involving the axial donor in a C4-symmetric, mono-capped, square antiprismatic cationic Eu complex, supported by calculations based on an electrostatic perturbation model, have been interpreted in terms of a predominant ligand polarisation interaction defined by observation of the hypersensitive J = 2 normalised emission intensity, in association with measurements correlating J = 1 band splitting and 1H NMR dipolar shifts that vindicate Bleaneys theory of magnetic anisotropy.
|Item Type:||Journal Article|
|Extra Information:||Some of the symbols may not have transferred correctly into this bibliographic record and/or abstract.|
|Academic Unit/Department:||Science > Life, Health and Chemical Sciences|
|Interdisciplinary Research Centre:||Centre for Earth, Planetary, Space and Astronomical Research (CEPSAR)
Biomedical Research Network (BRN)
|Depositing User:||James Bruce|
|Date Deposited:||30 Jun 2006|
|Last Modified:||07 Mar 2014 13:46|
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