Batsanov, Andrei S.; Bruce, James I.; Ganesh, Thota; Low, Paul J.; Kataky, Ritu; Puschmann, Horst and Steel, Patrick G.
|DOI (Digital Object Identifier) Link:||http://dx.doi.org/10.1039/b111628b|
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Hexadentate cyclen complexes of Sm(III), Eu(III) and Yb(III) have been prepared from 1,4-bis[(R)--methylbenzylaminocarbonylmethyl]-1,4,7,10-tetraazacycldodecane and characterised. The crystal structures of the isomorphous complexes of Eu(III) and Sm (III) have been determined. These may be electrochemically reduced to the +II oxidation state and employed in organic synthesis. However, no asymmetric induction was observed and this can be attributed to the fluxional nature of these complexes in solution and the limited asymmetric influence imparted by the N-(-methylbenzyl)acetamide chiral auxiliary.
|Item Type:||Journal Article|
|Extra Information:||Some of the symbols may not have transferred correctly into this bibliographic record.|
|Academic Unit/Department:||Science > Life, Health and Chemical Sciences
|Interdisciplinary Research Centre:||Centre for Earth, Planetary, Space and Astronomical Research (CEPSAR)
Biomedical Research Network (BRN)
|Depositing User:||James Bruce|
|Date Deposited:||30 Jun 2006|
|Last Modified:||14 Jan 2016 15:57|
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