Hill, Roger R.; Moore, Sharon A. and Roberts, David R.
|DOI (Digital Object Identifier) Link:||http://dx.doi.org/10.1039/b308525b|
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Photo-excited N-tosyl derivatives of phenylalanyl- and, more particularly, O-methyltyrosylmethylamides undergo electron transfer from aryl to tosyl groups whereas the photo-degradation of aliphatic analogues is initiated by electron transfer from the peptide bond, suggesting the latter as one possible reason for the rapid turnover of the D1 protein in biological water oxidation when the essential mediating role of tyrosine 116 in the PSII complex is inhibited.
|Item Type:||Journal Article|
|Copyright Holders:||2003 The Royal Society of Chemistry|
|Keywords:||photosystem II; electron transfer; photodegradation; peptides|
|Academic Unit/Department:||Science > Life, Health and Chemical Sciences
|Depositing User:||David Roberts|
|Date Deposited:||29 Jun 2006|
|Last Modified:||14 Jan 2016 15:56|
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