Cationic complexes of silicon and germanium with (O,S)-chelate ligands

Kalashnikova, Natalia A.; Bylikin, Sergey Yu.; Korlyukov, Aleksander A.; Shipov, Aleksander G.; Baukov, Yuri I.; Taylor, Peter G. and Bassindale, Alan R. (2012). Cationic complexes of silicon and germanium with (O,S)-chelate ligands. Dalton transactions , 2012(41), pp. 12681–12682.

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DOI (Digital Object Identifier) Link:	http://dx.doi.org/doi:10.1039/c2dt31554h
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Abstract

Synthesis and X-ray diffraction study of cationic bischelates MeSi(SCH₂CONMe₂)₂⁺Cl^- and MeGe(SCH₂CONMe₂)₂⁺Br^- are reported. According to X-ray data, the Si and Ge atoms in these compounds have distorted TBP environments with two coordinating oxygen atoms in axial positions.

Item Type:	Journal Article
Copyright Holders:	2012 The Royal Society of Chemistry
ISSN:	1477-9234
Funders:	Russian Foundation for Basic Research (grant No. 11-03-00655)
Academic Unit/Department:	Science > Life, Health and Chemical Sciences Other Departments > Other Departments
Item ID:	34654
Depositing User:	Peter Taylor
Date Deposited:	24 Oct 2012 10:10
Last Modified:	22 Nov 2012 17:12
URI:	http://oro.open.ac.uk/id/eprint/34654

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