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Cationic complexes of silicon and germanium with (O,S)-chelate ligands

Kalashnikova, Natalia A.; Bylikin, Sergey Yu.; Korlyukov, Aleksander A.; Shipov, Aleksander G.; Baukov, Yuri I.; Taylor, Peter G. and Bassindale, Alan R. (2012). Cationic complexes of silicon and germanium with (O,S)-chelate ligands. Dalton transactions , 2012(41) pp. 12681–12682.

DOI (Digital Object Identifier) Link: https://doi.org/10.1039/c2dt31554h
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Abstract

Synthesis and X-ray diffraction study of cationic bischelates MeSi(SCH2CONMe2)2+Cl- and MeGe(SCH2CONMe2)2+Br- are reported. According to X-ray data, the Si and Ge atoms in these compounds have distorted TBP environments with two coordinating oxygen atoms in axial positions.

Item Type: Journal Item
Copyright Holders: 2012 The Royal Society of Chemistry
ISSN: 1477-9234
Project Funding Details:
Funded Project NameProject IDFunding Body
Not SetNot SetRussian Foundation for Basic Research (grant No. 11-03-00655)
Academic Unit/School: Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM)
Other Departments > Vice-Chancellor's Office
Other Departments
Item ID: 34654
Depositing User: Peter Taylor
Date Deposited: 24 Oct 2012 10:10
Last Modified: 19 Dec 2017 10:03
URI: http://oro.open.ac.uk/id/eprint/34654
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