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Cationic complexes of silicon and germanium with (O,S)-chelate ligands

Kalashnikova, Natalia A.; Bylikin, Sergey Yu.; Korlyukov, Aleksander A.; Shipov, Aleksander G.; Baukov, Yuri I.; Taylor, Peter G. and Bassindale, Alan R. (2012). Cationic complexes of silicon and germanium with (O,S)-chelate ligands. Dalton transactions , 2012(41) pp. 12681–12682.

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Synthesis and X-ray diffraction study of cationic bischelates MeSi(SCH2CONMe2)2+Cl- and MeGe(SCH2CONMe2)2+Br- are reported. According to X-ray data, the Si and Ge atoms in these compounds have distorted TBP environments with two coordinating oxygen atoms in axial positions.

Item Type: Journal Article
Copyright Holders: 2012 The Royal Society of Chemistry
ISSN: 1477-9234
Project Funding Details:
Funded Project NameProject IDFunding Body
Not SetNot SetRussian Foundation for Basic Research (grant No. 11-03-00655)
Academic Unit/Department: Science > Life, Health and Chemical Sciences
Other Departments > Vice-Chancellor's Office
Interdisciplinary Research Centre: Biomedical Research Network (BRN)
Centre for Earth, Planetary, Space and Astronomical Research (CEPSAR)
Item ID: 34654
Depositing User: Peter Taylor
Date Deposited: 24 Oct 2012 10:10
Last Modified: 24 Nov 2014 12:13
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