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Martinho, Paulo N.; Harding, Charles J.; Müller-Bunz, Helge; Albrecht, Martin and Morgan, Grace G.
(2010).
DOI: https://doi.org/10.1002/ejic.200901183
Abstract
Thermal spin crossover (SCO) was induced in a high-spin FeIII complex by alkylation of the polyamino ligand backbone.The SCO profile was responsive to chain length with partial crossover observed with C6 alkylation and full transition upon lengthening to C12. No crossover was observed when the backbone was unfunctionalised, and all three complexes were obtained as unsolvated tetrafluoroborate salts.
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About
- Item ORO ID
- 34389
- Item Type
- Journal Item
- ISSN
- 1099-0682
- Keywords
- amphiphiles; spin crossover; iron; molecular switching; magnetic properties
- Academic Unit or School
-
Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM) - Copyright Holders
- © 2010 Wiley-VCH Verlag GmbH & Co.
- Depositing User
- Charlie Harding