Martinho, Paulo N.; Harding, Charles J.; Müller-Bunz, Helge; Albrecht, Martin and Morgan, Grace G.
(2010).
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| DOI (Digital Object Identifier) Link: | http://doi.org/10.1002/ejic.200901183 |
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Abstract
Thermal spin crossover (SCO) was induced in a high-spin FeIII complex by alkylation of the polyamino ligand backbone.The SCO profile was responsive to chain length with partial crossover observed with C6 alkylation and full transition upon lengthening to C12. No crossover was observed when the backbone was unfunctionalised, and all three complexes were obtained as unsolvated tetrafluoroborate salts.
| Item Type: | Journal Article |
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| Copyright Holders: | 2010 Wiley-VCH Verlag GmbH & Co. |
| ISSN: | 1099-0682 |
| Keywords: | amphiphiles; spin crossover; iron; molecular switching; magnetic properties |
| Academic Unit/Department: | Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences Faculty of Science, Technology, Engineering and Mathematics (STEM) |
| Item ID: | 34389 |
| Depositing User: | Charlie Harding |
| Date Deposited: | 24 Sep 2012 08:34 |
| Last Modified: | 02 Aug 2016 14:20 |
| URI: | http://oro.open.ac.uk/id/eprint/34389 |
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- Inducing spin crossover in amphiphilic iron(III) complexes. (deposited 24 Sep 2012 08:34) [Currently Displayed]
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