Martinho, Paulo N.; Harding, Charles J.; Müller-Bunz, Helge; Albrecht, Martin and Morgan, Grace G.
Inducing spin crossover in amphiphilic iron(III) complexes.
European Journal of Inorganic Chemistry(5),
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Thermal spin crossover (SCO) was induced in a high-spin
FeIII complex by alkylation of the polyamino ligand backbone.The SCO profile was responsive to chain length with partial crossover observed with C6 alkylation and full transition upon lengthening to C12. No crossover was observed when the backbone was unfunctionalised, and all three complexes were obtained as unsolvated tetrafluoroborate salts.
||2010 Wiley-VCH Verlag GmbH & Co.
||amphiphiles; spin crossover; iron; molecular switching; magnetic properties
||Science > Life, Health and Chemical Sciences
||24 Sep 2012 08:34
||14 Nov 2012 12:25
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Inducing spin crossover in amphiphilic iron(III) complexes. (deposited 24 Sep 2012 08:34)
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