Taylor, Peter G.; Bassindale, Alan R.; El Aziz, Youssef; Pourny, Manuel; Hursthouse, Michael B. and Coles, Simon J.
|DOI (Digital Object Identifier) Link:||http://dx.doi.org/doi:10.1039/C1DT11340B|
|Google Scholar:||Look up in Google Scholar|
A range of fluoride-encapsulated octasilsesquioxane cage compounds have been prepared using the TBAF route. Our studies suggest that whilst it is relatively straightforward to prepare fluoride-encapsulated octasilsesquioxane cage compounds with adjacent sp2 carbons, leading to a range of aryl and vinyl substituted compounds, the corresponding sp3 carbon derivatives are more capricious, requiring an electron withdrawing group that can stabilize the cage whilst not acting as a leaving group. Analysis by X-ray crystallography and solution 19F/29Si NMR spectroscopy of R8T8@F− reveal very similar environments for the encapsulated fluoride octasilsesquioxane cages. Migration of a fluoride ion from inside the cage to outside the cage without breaking the T8 framework and the possibility of encapsulating other anions within silsesquioxane cages have been also investigated.
|Item Type:||Journal Article|
|Copyright Holders:||2012 Royal Society of Chemistry|
|Academic Unit/Department:||Science > Life, Health and Chemical Sciences
Other Departments > Other Departments
Science > Physical Sciences
|Depositing User:||Peter Taylor|
|Date Deposited:||01 Feb 2012 17:42|
|Last Modified:||22 Nov 2012 17:12|
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