Berry, Frank J.; Coomer, Fiona C.; Hancock, Cathryn; Helgason, Őrn; Moore, Elaine A.; Slater, Peter R.; Wright, Adrian J. and Thomas, Michael F.
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|DOI (Digital Object Identifier) Link:||http://doi.org/10.1016/j.jssc.2011.04.011|
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Fluorination of the parent oxide, BaFeO3_δ with polyvinylidine fluoride gives rise to a cubic compound with a=4.0603(4) Å at 298 K. 57Fe Mössbauer spectra confirmed that all the iron is present as Fe3+. Neutron diffraction data showed complete occupancy of the anion sites, indicating a composition BaFeO2F, with a large displacement of the iron off-site. The magnetic ordering temperature was determined as TN=645±5 K. Neutron diffraction data at 4.2 K established G-type antiferromagnetism with a magnetic moment per Fe3+ ion of 3.95 μB. However, magnetisation measurements indicated the presence of a weak ferromagnetic moment that is assigned to the canting of the antiferromagnetic structure. 57Fe Mössbauer spectra in the temperature range 10–300 K were fitted with a model of fluoride ion distribution that retains charge neutrality of the perovskite unit cell.
|Item Type:||Journal Article|
|Copyright Holders:||2011 Elsevier Inc|
|Project Funding Details:||
|Extra Information:||NOTICE: this is the author’s version of a work that was accepted for publication in Journal of Solid State Chemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Solid State Chemistry, 184(6) 2011 10.1016/j.jssc.2011.04.011|
|Keywords:||BaFeO2F; Oxide fluoride; Canted antiferromagnet|
|Academic Unit/Department:||Science > Life, Health and Chemical Sciences
|Interdisciplinary Research Centre:||Centre for Earth, Planetary, Space and Astronomical Research (CEPSAR)
Biomedical Research Network (BRN)
|Depositing User:||Elaine Moore|
|Date Deposited:||02 Jun 2011 11:35|
|Last Modified:||23 Feb 2016 21:09|
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