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Electronic state spectroscopy of acetaldehyde, CH3CHO, by high-resolution VUV photo-absorption

Limão-Vieira, P.; Eden, S.; Mason, N. J. and Hoffmann, S. V. (2003). Electronic state spectroscopy of acetaldehyde, CH3CHO, by high-resolution VUV photo-absorption. Chemical Physics Letters, 376(5-6) pp. 737–747.

DOI (Digital Object Identifier) Link: http://dx.doi.org/10.1016/S0009-2614(03)01070-4
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Abstract

The high-resolution photo-absorption cross-section of CH3CHO has been measured using synchrotron radiation in the range 3.0–11 eV (413 nm > λ > 113 nm). Electronic state assignments have been suggested for each of the observed absorption bands incorporating both valence and Rydberg transitions. Valence transitions to the singlet and triplet states are assigned. Six Rydberg series have been assigned converging to the ionisation energy limit 10.229 eV. Rydberg orbitals of each series are classified according to the magnitude of the quantum defect (σ). The measured VUV cross-sections are used to derive the photolysis rates of acetaldehyde in the terrestrial atmosphere.

Item Type: Journal Article
Copyright Holders: 2003 Elsevier Science B.V.
ISSN: 0009-2614
Project Funding Details:
Funded Project NameProject IDFunding Body
Not SetNot SetEPSRC
Not SetNot SetNERC
Not SetNot SetCLRC
Academic Unit/Department: Science > Physical Sciences
Interdisciplinary Research Centre: Centre for Earth, Planetary, Space and Astronomical Research (CEPSAR)
eSTEeM
Item ID: 25739
Depositing User: Sam Eden
Date Deposited: 13 Apr 2011 13:44
Last Modified: 05 Mar 2014 10:29
URI: http://oro.open.ac.uk/id/eprint/25739
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