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Limão-Vieira, P.; Eden, S.; Mason, N. J. and Hoffmann, S. V.
(2003).
DOI: https://doi.org/10.1016/S0009-2614(03)01070-4
Abstract
The high-resolution photo-absorption cross-section of CH3CHO has been measured using synchrotron radiation in the range 3.0–11 eV (413 nm > λ > 113 nm). Electronic state assignments have been suggested for each of the observed absorption bands incorporating both valence and Rydberg transitions. Valence transitions to the singlet and triplet states are assigned. Six Rydberg series have been assigned converging to the ionisation energy limit 10.229 eV. Rydberg orbitals of each series are classified according to the magnitude of the quantum defect (σ). The measured VUV cross-sections are used to derive the photolysis rates of acetaldehyde in the terrestrial atmosphere.
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About
- Item ORO ID
- 25739
- Item Type
- Journal Item
- ISSN
- 0009-2614
- Project Funding Details
-
Funded Project Name Project ID Funding Body Not Set Not Set EPSRC (Engineering and Physical Sciences Research Council) Not Set Not Set NERC (Natural Environment Research Council) Not Set Not Set CLRC - Academic Unit or School
-
Faculty of Science, Technology, Engineering and Mathematics (STEM) > Physical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM) - Research Group
- Physics
- Copyright Holders
- © 2003 Elsevier Science B.V.
- Depositing User
- Sam Eden