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Limão-Vieira, P.; Eden, S.; Kendall, P. A.; Mason, N. J. and Hoffmann, S. V.
(2002).
DOI: https://doi.org/10.1016/S0009-2614(02)01651-2
Abstract
The photo-absorption spectrum of (CH3)2S has been measured using synchrotron radiation in the range 5.0–11 eV (250>λ>110 nm). Electronic state assignments have been suggested for each of the observed absorption bands incorporating both valence and Rydberg transitions. Four Rydberg series have been assigned converging to the ionisation potential limit 8.686 eV. Rydberg orbitals of each series are classified according to the magnitude of the quantum defect ( δ ). The measured vacuum-ultraviolet (VUV) cross-sections are used to derive the photolysis rate of (CH3)2S in the terrestrial atmosphere.
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About
- Item ORO ID
- 25735
- Item Type
- Journal Item
- ISSN
- 0009-2614
- Project Funding Details
-
Funded Project Name Project ID Funding Body Not Set Not Set EPSRC (Engineering and Physical Sciences Research Council) Not Set Not Set NERC (Natural Environment Research Council) Not Set Not Set CLRC - Academic Unit or School
-
Faculty of Science, Technology, Engineering and Mathematics (STEM) > Physical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM) - Research Group
- Physics
- Copyright Holders
- © 2002 Elsevier Science B.V.
- Depositing User
- Sam Eden