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Four independent structures of a pentacoordinate silicon species at different points on the Berry pseudorotation pathway

Bassindale, Alan R.; Sohail, M.; Taylor, Peter G.; Korlyukov, Alexander A. and Arkhipov, Dmitry E. (2010). Four independent structures of a pentacoordinate silicon species at different points on the Berry pseudorotation pathway. Chemical Communications, 46(19) pp. 3274–3276.

DOI (Digital Object Identifier) Link: https://doi.org/10.1039/C000803F
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Abstract

A new pentacoordinate silicon species containing two chelating ligands has been synthesized. The structures of four independent cations of the same compound correspond to different points on the Berry pseudorotation pathway. The percentage of square planar character varies between 19% and 40%.

Item Type: Journal Item
Copyright Holders: 2010 RSC
ISSN: 1359-7345
Academic Unit/School: Other Departments > Vice-Chancellor's Office
Other Departments
Faculty of Science, Technology, Engineering and Mathematics (STEM) > Life, Health and Chemical Sciences
Faculty of Science, Technology, Engineering and Mathematics (STEM)
Item ID: 25699
Depositing User: Peter Taylor
Date Deposited: 30 Dec 2010 14:21
Last Modified: 02 May 2018 13:22
URI: http://oro.open.ac.uk/id/eprint/25699
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