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Four independent structures of a pentacoordinate silicon species at different points on the Berry pseudorotation pathway

Bassindale, Alan R.; Sohail, M.; Taylor, Peter G.; Korlyukov, Alexander A. and Arkhipov, Dmitry E. (2010). Four independent structures of a pentacoordinate silicon species at different points on the Berry pseudorotation pathway. Chemical Communications, 46(19) pp. 3274–3276.

DOI (Digital Object Identifier) Link: http://dx.doi.org/10.1039/C000803F
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Abstract

A new pentacoordinate silicon species containing two chelating ligands has been synthesized. The structures of four independent cations of the same compound correspond to different points on the Berry pseudorotation pathway. The percentage of square planar character varies between 19% and 40%.

Item Type: Journal Article
Copyright Holders: 2010 RSC
ISSN: 1359-7345
Academic Unit/Department: Other Departments > Vice-Chancellor's Office
Science > Life, Health and Chemical Sciences
Interdisciplinary Research Centre: Centre for Earth, Planetary, Space and Astronomical Research (CEPSAR)
eSTEeM
Biomedical Research Network (BRN)
Item ID: 25699
Depositing User: Peter Taylor
Date Deposited: 30 Dec 2010 14:21
Last Modified: 24 Jul 2014 09:22
URI: http://oro.open.ac.uk/id/eprint/25699
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