Antunes, R.; Almeida, D.; Martins, G.; Mason, N. J.; Garcia, G.; Maneira, M. J. P.; Nunes, Y. and Limão-Vieira, P.
PDF (Version of Record)
- Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
|DOI (Digital Object Identifier) Link:||http://doi.org/10.1039/c004467a|
|Google Scholar:||Look up in Google Scholar|
Ion-pair formation in gaseous nitromethane (CH3NO2) induced by electron transfer has been studied by investigating the products of collisions between fast potassium atoms and nitromethane molecules using a crossed molecular-beam technique. The negative ions formed in such collisions were analysed using time-of-flight mass spectroscopy. The six most dominant product anions are NO2?, O?, CH3NO2?, OH?, CH2NO2? and CNO?. By using nitromethane-d3 (CD3NO2), we found that previous mass 17 amu assignment to O? delayed fragment, is in the present experiment may be unambiguously assigned to OH?. The formation of CH2NO2? may be explained in terms of dissociative electron attachment to highly vibrationally excited molecules.
|Item Type:||Journal Article|
|Copyright Holders:||2010 the Owner Societies|
|Academic Unit/Department:||Science > Physical Sciences
|Interdisciplinary Research Centre:||Centre for Earth, Planetary, Space and Astronomical Research (CEPSAR)|
|Depositing User:||Astrid Peterkin|
|Date Deposited:||19 Oct 2010 12:20|
|Last Modified:||23 Feb 2016 18:23|
|Share this page:|
► Automated document suggestions from open access sources
Download history for this item
These details should be considered as only a guide to the number of downloads performed manually. Algorithmic methods have been applied in an attempt to remove automated downloads from the displayed statistics but no guarantee can be made as to the accuracy of the figures.