Pearson, N. J.; Griffin, W. L.; Alard, O. and O'Reilly, S. Y.
The isotopic composition of magnesium in mantle olivine: Records of depletion and metasomatism.
Chemical Geology, 226(3-4) pp. 115–133.
We have investigated detailed Mg isotopic variations in the lithospheric mantle by analysing olivine in mantle-derived peridotite xenoliths and megacrysts. High-precision in situ analyses of Mg-26/Mg-24 and Mg-25/M-24 g are made using a laser-ablation microprobe and MC-ICPMS. Measurements are done using a standard-sample bracketing technique with an in-house olivine standard. Replicate analyses of this standard give a precision of 0.20 parts per thousand (2sd) for delta Mg-26 (=[(Mg-26/Mg-24)(sample)/ (Mg-26/Mg-24) (standard) -1] x 1000) and 0. 12 parts per thousand (2sd) for delta Mg-25. The analysed olivine grains represent the lithospheric mantle beneath Archean cratons (Siberia, Kaapvaal, Slave) and Phanerozoic fold belts (SE Australia). Results from olivines show significant heterogeneity in the lithospheric mantle: delta Mg-26 ranges from - 3.01 parts per thousand to + 1.03 parts per thousand and delta Mg-25 from - 1.59 parts per thousand to +0.51 parts per thousand, relative to the magnesium isotopic standard DSM-3. There is a broad trend from lighter Mg isotopic compositions in depleted xenoliths from Archean mantle to heavier Mg in the less depleted Phanerozoic samples. Samples with petrographic evidence of refertilisation (including modal metasomatism) show large ranges in delta Mg values within samples. Sheared peridotite xenoliths from the Kaapvaal and Slave Cratons show a shift to higher delta Mg associated with the introduction of fluids with an 'asthenospheric' signature. Olivine in the least metasomatised peridotites from SE Australia has isotopically light Mg, whereas olivine in cryptically and modally metasomatised peridotites (amphibole + apatite-bearing) becomes progressively heavier. both absolutely and relative to pyroxene and amphibole, with increasing degrees of metasomatism. The heterogeneity measured in individual samples suggests that Mg isotopic fractionations produced by processes of mantle metasomatism are preserved on the intra-grain scale, and the magnitude of the observed fractionations indicates that diffusion-related (kinetic) processes are important in controlling isotope fractionation at high temperatures. The in situ measurement of Mg isotopes provides a powerful new method for investigating processes in the mantle. (c) 2005 Elsevier B.V. All rights reserved.
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