Tindle, Andrew G. and Pearce, Julian A.
Petrogenetic modelling of in situ fractional crystallization in the zoned Loch Doon pluton, Scotland.
Contributions to Mineralogy and Petrology, 78(2) pp. 196–207.
The late Caledonian Loch Doon granitic intrusion ranges in composition from hypersthene diorite at the margin, through quartz diorite, granodiorite and granite to cordierite microgranite at its core. Petrogenetic modelling of trace element variations and least squares analysis of major elements indicate that two distinct magmas are involved, each magma controlled by crystallization of plag-opx-cpx-bio. Late stage rocks related to the second magma include the cordierite microgranites and aplites, which are interpreted as the final residue which crystallized rapidly after a build up and loss of volatiles.
Analyses of whole rocks and minerals for REE's and other elements of moderate-high ionic potential indicate that these elements are strongly controlled by minor phase crystallization; apatite, zircon, sphene and allanite are dominant at intermediate compositions but other accessory minerals such as monazite and xenotime may also become important at acid compositions.
It is probable that within each magma the mechanisms of crystal settling and filter pressing operated, the former being initially dominant, and the latter becoming more important with increasing degree of fractional crystallization.
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