Mota, R.; Parafita, R.; Maneira, M. J. P.; Mason, N. J.; Garcia, G.; Ribeiro, P. A.; Raposo, M. and Limao-Vieira, P.
|DOI (Digital Object Identifier) Link:||http://dx.doi.org/10.1093/rpd/ncl388|
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The understanding of radiation damage within cells, and thence mutagenesis, depends upon a detailed knowledge of the spectroscopy and dissociation dynamics of water. Results of a new study of the electronic state spectroscopy of water, using synchrotron radiation are reported. In order to gain some insight into how the spectroscopy and dissociation dynamics of water is influenced by its environment we also report photo-absorption spectra of water within thin films of poly(o-methoxyaniline) which have been suggested as a good mimic for biological membranes in the cellular environment. Comparison of these spectra with those of gaseous water and condensed amorphous water ice suggest that water in such films is similar to gaseous water and does not show the blue shift suggested in some cellular models. The lowest energy of OH production from dissociation of water in the cellular environment may therefore be around 6.7 eV (185 nm).
|Item Type:||Journal Article|
|Academic Unit/Department:||Science > Physical Sciences|
|Interdisciplinary Research Centre:||Centre for Earth, Planetary, Space and Astronomical Research (CEPSAR)
|Depositing User:||Astrid Peterkin|
|Date Deposited:||19 Jun 2008|
|Last Modified:||05 Mar 2014 10:29|
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